Furyl pyrazole amides

ABSTRACT

The present invention discloses amides and thioamides substituted in the α or β position with substituted pyrazoles which are useful as herbicides.

CROSS REFERENCE TO RELATED APPLICATION

This is a division of application Ser. No. 686,548, filed May 14, 1976, now U.S. Pat. No. 4,072,498, issued Feb. 7, 1978, which is a continuation in part of application Ser. No. 524,231, filed Nov. 15, 1974, now abandoned.

The present invention relates to furyl pyrazole amides, for which the essential material constituting a disclosure thereof is incorporated by reference here from U.S. Pat. application Ser. No. 686,548, filed May 14, 1976, now U.S. Pat. No. 4,072,498. 

We claim:
 1. A compound of the formula: ##STR1## where R₁ is hydrogen, alkyl of 1 to 7 carbon atoms, inclusive, haloalkyl of 1 to 7 carbon atoms, inclusive, phenyl, benzyl or cycloalkyl of 3 to 6 carbon atoms, inclusive, with the proviso that when R₁ is benzyl or cycloalkyl m = 0; R₂ and R₅ are the same or different and are hydrogen, halogen, alkyl of 1 to 6 carbon atoms, inclusive, haloalkyl of 1 to 6 carbon atoms, inclusive, or phenyl; R₁ and R₂ together with the attached carbon atom can be cycloalkyl of 3 to 6 carbon atoms, inclusive, when m = 0; m is 0 or 1 provided that when m = 0, R₁ is not hydrogen and when m = 1 at least one of R₂ or R₅ is hydrogen; R₃ is hydrogen, alkyl of from 1 to 8 carbon atoms, inclusive, phenyl or benzyl; R₄ is hydrogen or alkyl of from 1 to 6 carbon atoms, inclusive, and R₃ and R₄ can be joined together to form a heterocyclic ring selected from the group consisting of pyrrolidine, or piperidine; A and B are the same or different and are hydrogen, alkyl of from 1 to 6 carbon atoms, inclusive, phenyl, halogen, cyano, haloalkyl of 1 to 6 carbon atoms, inclusive, alkoxy or alkylthio in which the alkyl group is from 1 to 3 carbon atoms, inclusive, or trifluoromethyl and when adjacent can be joined to form a ring of from 5 to 7 carbon atoms, inclusive; where X is halogen, nitro, cyano, acetyl, dimethylcarbamoyl, alkyl, haloalkyl, alkoxy or carboalkoxy in which the alkyl group is from 1 to 3 carbon atoms, inclusive, phenyl, benzyl, 2-phenylethyl and n is 0, 1, or 2 or an acid addition salt thereof.
 2. A compound according to claim 1 which is 3-(2-furyl)-N,N,α,4-tetramethylpyrazole-1-acetamide.
 3. A compound according to claim 1 which is α-ethyl-3-(2-furyl)-N,N,4-trimethylpyrazole-1-acetamide.
 4. A compound according to claim 1 which is 3-(2-furyl)-N,N,4-trimethyl-α-propylpyrazole-1-acetamide.
 5. A compound according to claim 1 which is N,N-diethyl-3-(2-furyl)-α,α,4-trimethylpyrazole-1-acetamide.
 6. A compound according to claim 1 which is 3-(2-furyl)-N,α,α,4-tetramethylpyrazole-1-acetamide.
 7. A compound according to claim 1 which is 3-(2-furyl)-N,N,α,α,4-pentamethylpyrazole-1-acetamide. 